无电子传输层半透明钙钛矿太阳电池的仿真研究

Numerical simulation of electron transport layer-free semi-transparent perovskite solar cells

  • 摘要: 无电子传输层半透明钙钛矿太阳电池在叠层太阳电池的应用上有着良好的应用前景。本文利用SCAPS软件对无电子传输层半透明钙钛矿太阳电池进行建模仿真,从理论上分析器件性能提升的关键因素。仿真结果表明,为了得到高转换效率的器件,入光侧透明导电层(TCO)功函数应低于3.5 eV,背光侧TCO功函数应高于4.9 eV。同时,要降低钙钛矿薄膜缺陷密度至1×1015 cm-3以下。此外,TCO与钙钛矿薄膜界面、钙钛矿薄膜与Spiro-OMeTAD界面的缺陷态密度应分别控制在1×1016 cm-3和1×1019 cm-3以下。

     

    Abstract: Electron transport layer-free semi-transparent perovskite solar cells have excellent prospects for tandem solar cells.In this work, the electron transport layer-free semi-transparent perovskite solar cells were simulated using SCAPS software to analyze the key factors for device performance enhancement.The simulation results revealed that to obtain a high-performance device, the work function of front transparent conductive oxide (TCO) should be below 3.5 eV, and the work function of back TCO should be higher than 4.9 eV.Meanwhile, the defect density of perovskite layer should be reduced to below 1×1015 cm-3.In addition, the defect density of states at the interfaces of TCO/CH3 NH3 Pb(I0.775 Br0.225)3 and CH3NH3Pb(I0.775Br0.225)3/Spiro-OMeTAD should be controlled to less than 1×1016 and 1×1019 cm-3, respectively.

     

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