铪基薄膜铁电存储器改性研究进展

Progress in the Modification of Hafnium Thin Film Ferroelectric Memory

  • 摘要: 铁电存储器以其优良的特性如低功耗、高耐久性和非挥发存储等而成为人们的关注点。由于要处理海量资料,必须要有高密度的内存整合,因此存储介质往往很薄。然而,在膜层减薄的情况下,传统钙钛矿材料的铁电性能将急剧下降,这对高密度集成的应用带来了严重的困难。研究表明,正交相的氧化铪具有铁电性,不但与CMOS工艺兼容,而且其铁电性在超薄膜厚下仍然保持优良,为实现大规模生产奠定了基础。但是,它存在唤醒效应、印记效应及可靠性不足等问题。调控相结构和氧空位状态是提高铁电性能的关键。本文将从元素掺杂、应力影响、氧空位调控等多方面介绍铪基薄膜铁电存储器改性的研究。

     

    Abstract: Ferroelectric memory exhibiting excellent performance has attracted many attentions for its low power consumption, high endurance and non-volatile storage capability.Storage of a large amount of data requires high-density integration of memory devices, and the storage medium is getting thinner.However, the ferroelectric properties of conventional perovskite materials degrade if the storage medium is very thin, which is a great challenge to integrate storage device in high-density.Hafnium oxide in an orthorhombic (Pca21) phase exhibits ferroelectric properties that is well kept even if the thickness of hafnium oxide is 1 nm.Additionally, it is well compatible with CMOS fabrication processing, which facilitates large-scale integration of ferroelectric memory.Reliability, imprint and wake-up effects are problems of a hafnium oxide based ferroelectric memory, which are closely associated with crystal phases and status of oxygen vacancies.Therefore, this article introduces progress in hafnium oxide memory from doping, effects of mechanical stress and the modulation of oxygen vacancies.

     

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