耐碱隔膜在电解水制氢中的研究

Research on the application of alkali-resistant membrane to hydrogen production by water electrolysis

  • 摘要: 碱性电解水制氢技术因成本低、环境友好、可市场化等优势受到广泛关注。在碱性电解水系统结构中,隔膜处于阴、阳两极之间,通过影响氢氧根的传质过程和欧姆内阻,进而对碱性电解水制氢系统的性能造成影响。因此,开发具有高氢氧根电导率、强耐碱性以及优异氢、氧阻隔性的隔膜材料具有重要意义。本文对碱性电解水系统中常用的多孔隔膜、溶剂化离子传导膜和阴离子交换膜三个类别隔膜展开论述。从结构性能、电化学性能等角度,总结了碱性电解水系统用膜的研究进展并分析了所面临的技术难题,为之后开发用于碱性电解水的隔膜提供了新思路。

     

    Abstract: Alkaline water electrolysis technology for hydrogen has been widely concerned because of its low cost, friendly environment, and marketability.In the structure of the alkaline water electrolysis system, the membrane is located between the anode and cathode, which affects the mass transfer process and ohmic internal resistance of OH-, affecting the performance of the alkaline water electrolysis.As one of the core components of alkaline water electrolysis, it is of great significance to develop a membrane with high OH- conductivity, excellent alkali resistance, and gas barrier properties.This study discusses three types of membranes commonly used in alkaline water electrolysis: porous membrane, solvated ion conductive membrane, and anion exchange membrane.From the structural and electrochemical performance to the summary of the difficulty of water electrolysis membrane, which provides new ideas for the development of membranes for alkaline water electrolysis.

     

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