尖晶石型高熵氧化物的研究进展

Progresses of the research on spinel high entropy oxides

  • 摘要: 作为近几年发展起来的新型氧化物体系,尖晶石型高熵氧化物具有两个不同的Wyckoff位点,允许三价和二价阳离子同时存在,这一特点提升了材料在离子价态的可变范围,拓展了其性能的可调性。由于其具有组分可调性、稳定的单相结构和优异的热学、磁学、电学等性能,这类化合物受到国内外研究人员的关注,已被广泛用于电池、催化、储能等各领域。本文综述了尖晶石型高熵氧化物领域的最新研究进展,旨在分析并总结该领域的研究动态,特别是对其单相形成能力的影响因素、制备方法及其应用三个方面的进展进行了重点介绍。

     

    Abstract: As a new oxide system developed in recent years, spinel high entropy oxides (S-HEOs) have two different Wyckoff sites, which allow the coexistence of trivalent and divalent cations at the same time. Such a feature increases the range of valence changes and expands the tunability of the performance. Due to its component tunability, single-phase structure and excellent thermal, magnetic, electrical properties, S-HEOs have attracted the attention of researchers at home and abroad, and has been widely used in batteries, catalysis, energy storage and other fields. In this paper, the latest research progress in the field of S-HEOs is reviewed, and the purpose of this paper is to analyze and summarize the research trends in the field of S-HEOs, especially their single-phase formation ability, preparation methods and applications.

     

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