烯烃嵌段共聚物柔性相变材料的制备及控温性能研究

Preparation and temperature regulation performance of flexible phase change materials based on olefin block copolymers

  • 摘要: 柔性相变材料(FPCM)因其具有潜热储能特性和柔性特性,不仅能高效储能,还能与物体表面紧密贴合,可广泛应用于人体热管理与控温领域。本研究通过物理共混方法,采用烯烃嵌段共聚物(OBC)和十六烷微胶囊(M16)制备出复合相变材料(OM16)。结果表明,以1∶1.2比例制备的OM16-1.2具有一定柔性的同时,其相变焓值可以达到85.45 J/g、相变温度为16.97 ℃,在100次循环测试后相变焓值仅降低6.59%,表现出优异的循环稳定性;并且可以在173 ℃温度下,OM16具有良好的热稳定性。同时,10 g的OM16-1.2能实现约50 min的控温效果,显示出其在人体冷敷控温应用中的潜力。

     

    Abstract: Flexible phase change materials (FPCM) are widely used in the field of human thermal management and temperature control due to their latent heat energy storage and flexibility characteristics, which not only enable efficient energy storage, but also closely adhere to the surface of objects. In this study, a composite phase change material (OM16) was prepared using physical blending of olefin block copolymer (OBC) and hexadecane microcapsules (M16). The results indicate that OM16-1.2 prepared in a 1:1.2 ratio exhibits certain flexibility at low temperatures, with a phase change enthalpy of 85.45 J/g and a phase change temperature of 16.97 °C. After 100 cycles, the phase change enthalpy decreased by only 6.59%, demonstrating excellent cyclic stability. Additionally, it maintains good thermal stability at temperatures below 173 °C. Moreover, 10 g of OM16-1.2 can achieve temperature control for approximately 50 minutes, highlighting its potential for application in cold compress temperature regulation for the human body.

     

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