薄锂制造工艺前沿探索与应用前景展望

Frontier exploration of thin lithium manufacturing processes and prospects

  • 摘要: 锂金属电池凭借其超高理论容量(3860 mAh g−1)和极低电极电位(−3.04 V vs NHE),在化学储能领域展现出巨大应用前景。然而,锂枝晶不可控生长及电极体积剧烈膨胀等问题严重制约其实际应用。当前针对锂金属负极稳定化的研究虽取得显著进展,但普遍采用厚锂作为研究对象,这不仅导致活性材料利用率低下,还可能造成改性策略的评估偏差,难以满足高能量密度电池的设计需求。值得注意的是,实现薄锂(<50 μm)的规模化制备仍面临严峻挑战。本文从锂金属电池的发展展开,系统阐述实用化薄锂负极的发展必要性,重点综述薄锂制备技术及其稳定化策略的最新研究进展。最后,基于现有技术瓶颈提出薄锂金属电池的未来发展方向,为推进高安全、长寿命锂金属电池的产业化应用提供理论指导和技术参考。

     

    Abstract: Lithium metal batteries have emerged as a promising candidate for next-generation energy storage systems due to their ultrahigh theoretical capacity (3860 mAh g−1) and extremely low electrode potential (−3.04 V vs NHE). However, critical challenges including uncontrolled lithium dendrite growth and severe electrode volume expansion significantly hinder their practical implementation. Although substantial progress has been achieved in stabilizing lithium metal anodes, current research predominantly focuses on thick lithium (>200 μm), which not only results in low active material utilization but also introduces evaluation deviations for modification strategies, ultimately failing to meet the design requirements of high-energy-density batteries. Notably, the scalable fabrication of thin lithium foils (<50 μm) remains a formidable challenge. This review commences with the development of lithium-metal batteries and systematically expounds on the necessity of the development of practical thin lithium anodes, then comprehensively summarizes recent advancements in thin lithium fabrication techniques and stabilization strategies. Finally, future research directions are proposed to address existing technical bottlenecks, offering both theoretical guidance and technical references for advancing the industrial application of safe and durable lithium metal batteries.

     

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