锡基钙钛矿太阳电池的研究与展望

Research and Prospect of Tin-based Perovskite Solar Cells

  • 摘要: 铅基钙钛矿材料由于具有独特的光学和电学特性成为光电应用的新星材料。但是铅金属对环境不友好,制约着其商业化的发展。而锡基钙钛矿材料由于其具有低毒性、较宽的吸收光谱、更高的迁移率使其成为有希望实现商业化的光伏器件。目前,锡基钙钛矿太阳电池的光电转换效率(PCE)已超过14%,但远远不及铅基钙钛矿器件。本综述讨论了锡基钙钛矿材料不同组分工程、不同钙钛矿器件结构以及不同添加剂对锡基钙钛矿器件性能和稳定性的影响,并对钙钛矿太阳电池的发展进行总结和展望,旨在为制备高效稳定的锡基钙钛矿太阳电池提供有益的启示。

     

    Abstract: Organic-inorganic halide perovskite materials have emerged as an excellent material for the optoelectronic applications because of their unique optical and electrical properties. However, the heavy metal character of lead is unfriendly to the environment, which restricts the commercial applications. Tin(Sn)-based perovskite materials are the promising candidates due to their low toxicity, broad absorption and higher mobility. Up to now, the highest power conversion efficiency(PCE) of Sn perovskite solar cells has exceeded 14%, which is much lower than lead-based perovskite devices. This review discusses the effects of component engineering of tin-based perovskite, the perovskite device structures and the additives on the performance and device stability of tin-based perovskite devices. Finally a summary and outlook of the development of perovskite solar cells are given at the end of the paper that provides helpful insights for the preparation of efficient and stable Sn-based perovskite solar cells.

     

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