片状ZnO/ZIF-8异质结的正丁醇气敏性能增强研究
Study on enhancement of n-butanol gas sensing performance of sheet ZnO/ZIF-8 heterojunction
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摘要: 本文利用水热法,以2-甲基咪唑和氧化锌(ZnO)纳米片为原料原位合成了片状ZnO/ZIF-8异质结复合材料。利用X射线衍射(XRD)、红外光谱(IR)和扫描电子显微镜(SEM)对样品进行表征,并通过气敏性能测试仪系统研究了样品的气敏性能,进一步探讨了ZnO/ZIF-8气敏性能增强的可能机理。气敏性能分析结果表明:与纯相ZnO (其最佳工作温度为180℃)相比,ZnO/ZIF-8的最佳工作温度降低为160℃。在最佳工作温度下,ZnO/ZIF-8对正丁醇表现出了优异的选择性,对200 ppm正丁醇的响应达到了76.778。在5~200 ppm正丁醇浓度范围内,ZnO/ZIF-8的灵敏度与浓度的相关性近似呈线性,重复性及稳定性良好,适合检测低浓度的正丁醇气体。Abstract: Using 2-methylimidazole and ZnO nano sheets as raw materials, sheet ZnO/ZIF-8 heterojunction composites were synthesized by hydrothermal method in this work.The samples were characterized by X-ray diffraction (XRD), infrared spectroscopy (IR) and scanning electron microscopy(SEM).The gas sensing performance of the samples was systematically studied by gas sensing performance tester, and the possible mechanism of the enhanced gas sensing performance of ZnO/ZIF-8 was further discussed.The results of gas sensing performance analysis show that the optimum working temperature of ZnO/ZIF-8 is 160℃, lower than that of pure ZnO (its optimum working temperature is 180℃).At the optimum operating temperature, ZnO/ZIF-8 exhibited excellent selectivity for n-butanol, with a response of 76.778 to 200 ppm n-butanol.In the concentration range of 5-200 ppm n-butanol, the sensitivity of ZnO/ZIF-8 is approximately linear in correlation with the concentration, with good repeatability and stability, which is suitable for detecting low concentration n-butanol gas.